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EPR/UV-VIS-NIR Spectroelectrochemical Examination of the Association Properties of Thienoacene-Bridged Tetrathiafulvalenes Supported by DFT Calculations
Lušpai, Karol ; Rapta, P. ; Zalibera, M. ; Darvasiová, D. ; Lukeš, V.
This work was focused on the EPR/UV-VIS-NIR spectroelectrochemical examination of\nassociation properties of radical cations electrochemically produced from tetrathiafulvalene\n(TTF) derivatives, in relation to the molecular structure, mainly the number and orientation of\nthiophene rings in the spacer between fulvalene redox centers. Results from EPR/UV-VIS-NIR\nspectroelectrochemistry were supported by DFT calculations.

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